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Using the Technology
Examples in
Conventional Reservoirs and Marine Shales
The basic idea of our technology is simple. Oil
converts to natural gas catalytically, promoted by
trace metals in sedimentary rocks. We can predict
the amount of gas generated in a rock (% Gas) from
its catalytic activity (Activity),
which we measure, and the rock’s estimated
temperature at depth (Figures 1 & 2).
Example 1: Predicting Gas in
Reservoir Rocks, Gulf of Mexico Model
Consider two reservoirs, A1 and B1, both targeted
for drilling at 13,000 ft. Assuming they have
hydrocarbons, which has the highest probability for
oil (assuming there is no market for gas in this
basin)? Both are deltaic sandstones, and we have
well cuttings from reservoirs in the basin. An
Activity Log of each well gives A1 with an Activity
of 10 ppb (parts-per-billion active metal) and B1
with 100 ppb. We then use Figure 1, the Model for
deltaic basins, to predict oil in A1 (40% Gas) and
100% gas in B1.

Figure 1.
Deltaic Basin Model, Gulf of Mexico.
Example 2: Predicting Gas in a Marine
Shale, Palo Duro Basin, Texas.
The Palo Duro is similar to the Ft Worth basin in
several respects, and we were interested in
approximating its shale-gas potential compared to
the Ft Worth Basin. We obtain cuttings from old
wells in Brisco, Floyd, and Motley Counties from the
Bureau of Economic Geology here in Houston, and
analyzed them for Activity. The Barnett Shale Model
for Ft Worth basin had correctly predicted % Gas in
Montague, Wise, and Johnson Counties (See Activity
Logs and Figure 2). We used this Model and the
Activity Logs (Activity vs Depth) and maturities of
the Palo Duro to sketch the stratigraphic and
geographic opportunities for shale gas in the Bend
Group shales of the Palo Duro. The analysis gave a
clear picture (proprietary) of the basin’s gas
potential relative to the Barnett Shale in Ft Worth
Basin. This evaluation was completed in 4 weeks at a
cost of under $10,000.

Figure 2.
Barnett Shale Model, Ft Worth Basin. The curve
marked M is the Activity Curve for Montague County,
W is the curve for Wise County, and J is the curve
for Johnson County. The Model correctly predicts oil
in Montague, wet gas in Wise and dry gas in Johnson.
Activity Logs
Activity Logs are well logs showing rock activity
with depth. They are generated from cuttings,
typically four or five samples within a
stratigraphic unit. Activity Logs of strategic wells
will map oil and gas in three dimensions, thus
highlighting opportunities for hydrocarbon-specific
(oil or gas) drilling. This is totally new in
exploration, with powerful implications where oil or
gas carries a premium.
Figure 3 shows the oil to dry gas trend in the
Barnett Shale, Ft Worth Basin. Wells in three
counties within the trend were selected for
analysis, one from Montague County in the north
where the Barnett contains oil, the second south of
it in Wise County with wet gas, and the third
southeast of it in Johnson County producing dry gas.
The three Activity Logs are shown in Figure 4,
superimposed for comparison. Taking average
activities from the logs, and average maturities in
these wells (Wise and Johnson are ~ 1.1% Ro,
Montague ~ 0.9% Ro), the Model in Figure 2 correctly
shows oil for Montague, wet gas for Wise, and dry
gas for Johnson.

Figure
3. Map of the Barnett Shale (Mississippian) in
the Ft Worth Basin showing the oil to dry gas trend
across the basin. Courtesy of Dan Jarvie, Humble
Geochemical Services.

Figure
4. Activity Logs of Three Wells in the Barnett
Shale, Ft Worth Basin.
Two things stand out in these logs. First, the
well in Montague County is uniformly inactive, which
explains why oil is the dominant hydrocarbon in this
region of the Barnett. Second, there are large
stratigraphic variations in activity (~ 30%
variance) over narrow depth intervals in both Wise
and Johnson Counties. It is not analytical variance
because the Assay’s reproducibility is within ~ 5%.
We believe it is reflecting the oxic/anoxic
variations in depositional environments. Consistent
with this interpretation, we see a strong
correlation between rock Activity and the Rock-Eval
ratio HI/(HI+OI) (Figure 5).
Activity Logs add new stratigraphic information
to standard logs, namely the rock’s capacity to
convert oil to gas at depth. Like other rock
properties, Activity is easily correlated between
wells and mapped basin-wide. Coupled with the Models
in Figures 1 & 2, Activity maps are powerful
predictors of hydrocarbon composition in un-drilled
reservoirs.

Figure
5. Marine shales from Bend Group (Penn), Palo
Duro Basin, Texas. The data reflects over 2,000 ft
of section from Amerada Bernie well. Activity
calculated from cuttings obtained from Bureau of
Exconomic Geology, Houston. High values of HI
reflect reducing condition that should activate
metals and high values in OI reflect oxic
environments that should deactivate metal.
Frank Mango, PhD
Founder, President, and CEO
Petroleum Habitats, LLC
281-497-0384
f mango@petrohabs.rr.com
www.petroleumhabitats.com
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